Phone: +49 (0) 30 2093 7453
Filippo Giovanni Fabozzi
Design and Generation of On-Surface Conjugated 2D-Polymers
Two-Dimensional Polymers (2D-Polymers) are covalently bonded, molecularly thin macromolecules composed by organic building blocks. Thanks to their high in-plane dimensionality and high extension into the second dimension, 2D-Polymers promises to be next generation systems for (opto)electronics, sensors and separation. However, unlike their bulk counterpart Covalent Organic Frameworks (2D-COFs) and inorganic 2D-Materials (2DMs) their synthesis remains still extremely challenging. My PhD thesis aim to develop Dynamic Covalent Chemistry (DCC) for conjugated 2D-Polymer synthesis, as well develop new organic molecular building blocks for On-Surface 2D-Polymerization methods based on solid-liquid interface using different substrate such as HOPG, Graphene and other 2DMs. Formation of new materials as on-surface 2D-Polymers, open the way to the development of new technologies.
Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Eliminationfor the Synthesis of Vinylene-Linked 2D Covalent Organic Frameworks
S. Xu, Z. Liao, A. Dianat, S.W. Park, M. A. Addicoat, Y. Fu, D. L. Pastoetter, F. G. Fabozzi, Y. Liu, G. Cuniberti, M. Richter, S. Hecht, X. Feng*
Angew. Chem. Int. Ed. 2022, 61, e202202492.